Delete the single quotes, and add a ‘double equal’:
Tz=solve(Tz == (((xiz*(QH-deltaQH))./(M1.*(1+gammar)))+mcphayvc.*Tc)./(betaz.*mcphayphayvz), Tz)
That will at least not throw the same error.


Delete the single quotes, and add a ‘double equal’:
Tz=solve(Tz == (((xiz*(QH-deltaQH))./(M1.*(1+gammar)))+mcphayvc.*Tc)./(betaz.*mcphayphayvz), Tz)
That will at least not throw the same error.
syms Ta Tc alpha gammar Tz xiz QH deltaQH M1 betaz mcv=19.806+(0.00419/2).*Ta mcphayphayvz=19.806+(0.00419/2).*Tz+0.5.*Tz.*((360.34+252.4*alpha)^(10^-5)) mcphayvc=(mcv+gammar.*mcphayphayvz)./(1+gammar) eqn = Tz==(((xiz*(QH-deltaQH))./(M1.*(1+gammar)))+mcphayvc.*Tc)./(betaz.*mcphayphayvz); Tzsol = solve(eqn, Tz)
Note that Ta Tc gammar must be scalar values for this purpose. If they were arrays then the solve() would be trying to find one single Tz that solved all of the values simultaneously.
If you are trying to get a solution for each corresponding Ta, Tc, gammar, then you can
subs(Tzsol, {Ta, Tc, gammar}, {Ta_array, Tc_array, gammar_array})
Also note that a pair of solutions are found. It looks like it might be two solutions for a quadratic.
If betaz is an array then you need to
syms Ta_s Tc_s alpha gammar_s Tz xiz QH deltaQH M1 betaz_s
mcv=19.806+(0.00419/2).*Ta_s
mcphayphayvz=19.806+(0.00419/2).*Tz+0.5.*Tz.*((360.34+252.4*alpha)^(10^-5))
mcphayvc=(mcv+gammar_s.*mcphayphayvz)./(1+gammar_s)
eqn = Tz==(((xiz*(QH-deltaQH))./(M1.*(1+gammar_s)))+mcphayvc.*Tc_s)./(betaz_s.*mcphayphayvz);
Tzsol = solve(eqn, Tz)
Tz = double( subs(Tzsol, {Ta_s, Tc_s, gammar_s, betaz_s}, {Ta, Tc, gammar, betaz}) );
If you only want one particular location you could
Tz5401 = double( subs(Tzsol, {Ta_s, Tc_s, gammar_s, betaz_s}, {Ta(5401), Tc(5401), gammar(5401), betaz(5401)}) );
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